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Both fall under WADA Code S0, the non-approved-substances category

Breastfeeding Methylcobalamin is distributed into breast milk in amounts similar to those in maternal plasma, and distribution in breast milk allows for adequate intakes of methylcobalamin by breastfeeding infants

10.1016/j.cell.2011.10.018 Cell 177 WangZ

For larger doses above 50 units, you might prefer the 1 mL syringe for its full scale

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If you experience severe reactions such as an irregular heartbeat or trouble breathing, stop use immediately and consult your healthcare provider